MALLINCKRODT -- MANGANESE SULFATE -- 6810-00N034395
===================== Product Identification ===================== Product ID:MANGANESE SULFATE MSDS Date:04/06/1989 FSC:6810 NIIN:00N034395 === Responsible Party === Company Name:MALLINCKRODT Box:800 City:PARIS State:KY ZIP:40362 Country:US Info Phone Num:314-539-1600 Emergency Phone Num:314-539-1600 CAGE:ZA916 === Contractor Identification === Company Name:MALLINCKRODT MEDICAL, INC Address:2703 WAGNER PLACE Box:M City:MARYLAND HEIGHTS State:MO ZIP:63043 Country:US Phone:314-770-7800 CAGE:ZA916 Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:MANGANESE, MONOSULFATE, MONOHYDRATE; CAS:10034-96-5 RTECS #:OP0893500 Ingred Name:MANGANESE (II) SULFATE (1:1) CAS:7785-87-7 RTECS #:OP1050000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:MAY IRRIT RESP TRACT. ABSORP OF INORGANIC MANGANESE SALTS THRU LUNGS IS POOR BUT MAY OCCUR IN CHRONIC POISONING. INGEST:EXCESS AMTS MAY CAUSE ABDOM PAIN/NAUS. POORLY ABSORBED THRU GUT, INO RGANIC MANGANESE SALTS MAY PRDCE HYPOGLYCEMIA & DECREASED CALCIUM BLOOD LEVELS SHOULD ABSORPTION OCCUR.(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:SKIN:NO ADVERSE EFTS EXPECTED.EYE:NO ADVERSE EFTS EXPECTED BUT DUST MAY CAUSE MECH IRRIT.CHRONIC EXPOS:CHRONIC MANGANESE POIS CAN RESULT FROM EXCESS INHAL EXPOS TO MANGANESE DUST & INVOLVES I MPAIRMENT OF CNS.EARLY SYMP INCL SLUGGISHNESS/SLEEPINESS/WEAK IN LEGS.ADVANCED CASES HAVE SHOWN FIXED (SUPP DATA) Medical Cond Aggravated by Exposure:PERSONS WITH IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECT OF THIS SUBSTANCE. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. GET MD ATTN FOR ANY BRTHG DIFFICULTY. INGEST:INDUCE VOM IMMED BY GIVING TWO GLASSES OF WATER & STICKING FINGER DOWN THROAT. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSO N. CALL PHYSICIAN IMMED. SKIN:WASH EXPOSED AREA W/SOAP & WATER. GET MD ADVICE IF IRRIT DEVELOPS. EYE:WASH THORO W/RUNNING WATER FOR AT LEAST 15 MIN. GET MD ADVICE IF IRRITATION DEVELOPS. ===================== Fire Fighting Measures ===================== Flash Point:NON-HAZARDOUS Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE AN EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP AND CONTAINERIZE FOR RECLAMATION OR DISPOSAL. VACUUMING OR WET SWEEPING MAY BE USED TO AVOID DUST DISPERSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED CONTAINER, STORED IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF THE TLV IS EXCEEDED, A NIOSH/MSHA APPROVED DUST/MIST RESPIRATOR MAY BE WORN UP TO TEN TIMES THE TLV. CONSULT RESPIRATOR SUPPLIER FOR DETAILS. Ventilation:A SYS OF LOCAL & GENERAL EXHAUST IS REC TO KEEP EMPLOYEE EXPOS BELOW. LOCAL EXHAUST PREFERRED. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:CHEMICAL WORKERS GOGGLES . Other Protective Equipment:CLEAN BODY-COVERING CLOTHING. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health BP:1562F, 850C DECOMPOSES. EFTS OF OVEREXP:FACIAL EXPRESSION, EMOTIONAL DISTURBANCES, SPASTIC GAIT, AND FALLING. REPEATED INGESTIONS MAY CAUSE LETHARGY AND EDEMA. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:SUPP DATA Melt/Freeze Pt:M.P/F.P Text:1292F,700C Spec Gravity:2.95 Solubility in Water:SOLUBLE Appearance and Odor:PALE PINK GRANULAR POWDER. ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES POWDERED METALS, STRONG OXIDIZERS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:EMITS TOXIC FUMES OF SULFUR AND MANGANESE OXIDES WHEN HEATED TO DECOMPOSITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECLAMATION MAY BE DELIVERED TO AN APPROVED WASTE DISPOSAL FACILITY. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS . Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.